Advance Chemistry : The Gas laws

Wednesday, May 20, 2020

The Gas laws

  The Gas laws 

(A) Boyle's law -
 This law is given by the scientist Robert Boyle in 1662.
According to this law-
 The volume of a given mass of a gas is inversely proportional to its pressure provided the temperature remains constant.
   
                                                                           1                                           v     =    -----                 ( at constant                 p                temperature)  
                          
Or,     pv =  k = constant

Let the pressure and volume of any  gas is p   and V  and the 
                     1            1
 pressure and volume    of the same amount of the same gas be p  and v      then -
  2          2  

    p   v    =   p    v  = constant
      1    1         2    2

 (B) Charles' law-

   This law is given by the scientist J. Charles in 1787.
According to this law-

At constant pressure, the volume of a given mass of a gas is directly proportional to its absolute temperature.
     V   ~  T  (at constant pressure)
Or,    V = kT

               V 
 Or,       ----  = k
               T 

                V         V 
                  1          2
Or,        ------  =  -----
                T           T 
                  1            2


 (C) Gay Lussac's law-
 This law is given by the scientist Gay Lussac in 1802.
According to this law-
     At constant volume, the pressure of a given mass of a gas is directly proportional to its absolute temperature.
   P ~  T ( at constant volume)

Or,    P = kT

               P 
 Or,       ----  = k
               T 

                P          P
                  1          2
Or,        ------  =  -----
                T           T 
                   1           2

 (D) Avogadro's law-

This law is given by the scientist Amedeo Avogadro in 1811.
According to this law-
     Equal volume of all gasses contain equal number of molecules under similar conditions of temperature and pressure.
  
   V   ~  n


                V         V 
                  1          2
Or,        ------  =  -----
                n           n
                  1            2

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